catena-Poly[[[bis(2,2′-bipyridine)manganese(II)]-μ4-3,3′-sulfanediyldipropionato] bis(perchlorate)]
نویسنده
چکیده
The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2'-bipyridine ligands and two O atoms of two different 3,3'-sulfanediyldipropionate (L) ligands, with the O atoms in cis positions. The two carboxyl-ate groups of each L ligand, which adopt a syn-anti coordination mode, combine with four Mn(II) atoms, yielding one-dimensional chains extending along [010].
منابع مشابه
μ-Oxalato-bis[bis(2,2′-bipyridine)manganese(II)] bis(perchlorate) 2,2′-bipyridine solvate
The unit cell of the title compound, [Mn(2)(C(2)O(4))(C(10)H(8)N(2))(4)](ClO(4))(2)·C(10)H(8)N(2), consists of a binuclear cation, two perchlor-ate anions, and one solvent 2,2'-bipyridine (bpy) mol-ecule. In the complex cation [Mn(2)(C(2)O(4))(C(10)N(2)H(8))(4)](2+), two Mn(II) atoms are bridged by a bis-(bidentate) oxalate ligand, each Mn(II) atom being further coordinated by two bpy ligands i...
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In the polymeric title complex, {[Mn(O(2)CC(6)H(4)-p-OH)(2)(C(10)H(8)N(2))]·C(10)H(8)N(2)·2H(2)O}(n), the Mn(II) atom is coordinated in a distorted octa-hedral geometry defined by four O atoms from three different carboxyl-ate ligands and two trans-N atoms from two 4,4'-bipyridine ligands. In the crystal structure, an extensive range of O-H⋯O and O-H⋯N hydrogen bonds link the complex and all no...
متن کاملCrystal structure of bis(μ-2-benzoylbenzoato-κ2 O:O′)bis[bis(2,2′-bipyridine-κ2 N,N′)manganese(II)] bis(perchlorate)
The title compound, [Mn2(C6H5COC6H4COO)2(C10H8N2)4](ClO4)2, comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn(II) atoms are bridged by two O atoms of two different 2-benzoyl-benzoate ligands, each Mn(II) atom being further coordinated by two 2,2'-bi-pyridine (bipy) ligands in a distorted octa-hedral environment. Within the binuclear mol-ecule...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010